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Structure/property correlations in the new ferroelectric Bi5PbTi3O14Cl and related layered oxyhalide intergrowth phases

Research output: Contribution to journalArticlepeer-review

DOI

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Structure/property correlations in the new ferroelectric Bi5PbTi3O14Cl and related layered oxyhalide intergrowth phases. / Kusainova, AM; Yu, S; Irvine, John Thomas Sirr; Lightfoot, Philip.

In: Journal of Materials Chemistry, Vol. 12, 2002, p. 3413-3418.

Research output: Contribution to journalArticlepeer-review

Harvard

Kusainova, AM, Yu, S, Irvine, JTS & Lightfoot, P 2002, 'Structure/property correlations in the new ferroelectric Bi5PbTi3O14Cl and related layered oxyhalide intergrowth phases', Journal of Materials Chemistry, vol. 12, pp. 3413-3418. https://doi.org/10.1039/b208245d

APA

Kusainova, AM., Yu, S., Irvine, J. T. S., & Lightfoot, P. (2002). Structure/property correlations in the new ferroelectric Bi5PbTi3O14Cl and related layered oxyhalide intergrowth phases. Journal of Materials Chemistry, 12, 3413-3418. https://doi.org/10.1039/b208245d

Vancouver

Kusainova AM, Yu S, Irvine JTS, Lightfoot P. Structure/property correlations in the new ferroelectric Bi5PbTi3O14Cl and related layered oxyhalide intergrowth phases. Journal of Materials Chemistry. 2002;12:3413-3418. https://doi.org/10.1039/b208245d

Author

Kusainova, AM ; Yu, S ; Irvine, John Thomas Sirr ; Lightfoot, Philip. / Structure/property correlations in the new ferroelectric Bi5PbTi3O14Cl and related layered oxyhalide intergrowth phases. In: Journal of Materials Chemistry. 2002 ; Vol. 12. pp. 3413-3418.

Bibtex - Download

@article{e4826688286549d598d625d08c4aba9b,
title = "Structure/property correlations in the new ferroelectric Bi5PbTi3O14Cl and related layered oxyhalide intergrowth phases",
abstract = "The crystal structure and electrophysical properties of the layered intergrowth phase Bi5PbTi3O14Cl have been studied using powder neutron diffraction, ac impedance and second harmonic generation methods. This phase adopts a structure based on a regular intergrowth of Aurivillius-like and Sillen-like blocks in the layer sequence ...[M2O2][M2Ti3O10][M2O2][ Cl]..., and is therefore closely structurally related to the well-known ferroelectric Bi4Ti3O12. The phase adopts the polar orthorhombic space group P2an at temperatures below 590 degreesC, and transforms directly to a centrosymmetric tetragonal phase, space group P4/mmm, at that temperature. This abrupt structural phase transition is consistent with a sudden loss of SHG signal and a dielectric maximum at the same temperature. The structural features and electrophysical behaviour of this phase in relation to Bi4Ti3O12 and related layered oxides/oxyhalides are discussed.",
keywords = "STRUCTURE REFINEMENT, BI4TI3O12, BI4NBO8CL",
author = "AM Kusainova and S Yu and Irvine, {John Thomas Sirr} and Philip Lightfoot",
year = "2002",
doi = "10.1039/b208245d",
language = "English",
volume = "12",
pages = "3413--3418",
journal = "Journal of Materials Chemistry",
issn = "0959-9428",
publisher = "Royal Society of Chemistry",

}

RIS (suitable for import to EndNote) - Download

TY - JOUR

T1 - Structure/property correlations in the new ferroelectric Bi5PbTi3O14Cl and related layered oxyhalide intergrowth phases

AU - Kusainova, AM

AU - Yu, S

AU - Irvine, John Thomas Sirr

AU - Lightfoot, Philip

PY - 2002

Y1 - 2002

N2 - The crystal structure and electrophysical properties of the layered intergrowth phase Bi5PbTi3O14Cl have been studied using powder neutron diffraction, ac impedance and second harmonic generation methods. This phase adopts a structure based on a regular intergrowth of Aurivillius-like and Sillen-like blocks in the layer sequence ...[M2O2][M2Ti3O10][M2O2][ Cl]..., and is therefore closely structurally related to the well-known ferroelectric Bi4Ti3O12. The phase adopts the polar orthorhombic space group P2an at temperatures below 590 degreesC, and transforms directly to a centrosymmetric tetragonal phase, space group P4/mmm, at that temperature. This abrupt structural phase transition is consistent with a sudden loss of SHG signal and a dielectric maximum at the same temperature. The structural features and electrophysical behaviour of this phase in relation to Bi4Ti3O12 and related layered oxides/oxyhalides are discussed.

AB - The crystal structure and electrophysical properties of the layered intergrowth phase Bi5PbTi3O14Cl have been studied using powder neutron diffraction, ac impedance and second harmonic generation methods. This phase adopts a structure based on a regular intergrowth of Aurivillius-like and Sillen-like blocks in the layer sequence ...[M2O2][M2Ti3O10][M2O2][ Cl]..., and is therefore closely structurally related to the well-known ferroelectric Bi4Ti3O12. The phase adopts the polar orthorhombic space group P2an at temperatures below 590 degreesC, and transforms directly to a centrosymmetric tetragonal phase, space group P4/mmm, at that temperature. This abrupt structural phase transition is consistent with a sudden loss of SHG signal and a dielectric maximum at the same temperature. The structural features and electrophysical behaviour of this phase in relation to Bi4Ti3O12 and related layered oxides/oxyhalides are discussed.

KW - STRUCTURE REFINEMENT

KW - BI4TI3O12

KW - BI4NBO8CL

UR - http://www.scopus.com/inward/record.url?scp=0036922272&partnerID=8YFLogxK

U2 - 10.1039/b208245d

DO - 10.1039/b208245d

M3 - Article

VL - 12

SP - 3413

EP - 3418

JO - Journal of Materials Chemistry

JF - Journal of Materials Chemistry

SN - 0959-9428

ER -

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