Synthesis and structure determination from an extremely small single crystal of a new layered gallium phosphate

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Synthesis and structure determination from an extremely small single crystal of a new layered gallium phosphate. / Wragg, DS; Morris, Russell Edward.

In: Journal of Physics and Chemistry of Solids, Vol. 62, 07.2001, p. 1493-1497.

Research output: Contribution to journal › Article › peer-review

Harvard

Wragg, DS & Morris, RE 2001, 'Synthesis and structure determination from an extremely small single crystal of a new layered gallium phosphate', Journal of Physics and Chemistry of Solids, vol. 62, pp. 1493-1497.

APA

Wragg, DS., & Morris, R. E. (2001). Synthesis and structure determination from an extremely small single crystal of a new layered gallium phosphate. Journal of Physics and Chemistry of Solids, 62, 1493-1497.

Vancouver

Wragg DS, Morris RE. Synthesis and structure determination from an extremely small single crystal of a new layered gallium phosphate. Journal of Physics and Chemistry of Solids. 2001 Jul;62:1493-1497.

Author

Wragg, DS ; Morris, Russell Edward. / Synthesis and structure determination from an extremely small single crystal of a new layered gallium phosphate. In: Journal of Physics and Chemistry of Solids. 2001 ; Vol. 62. pp. 1493-1497.

Bibtex - Download

@article{0f5dc0cb6d804346b882c6d222d1d604,

title = "Synthesis and structure determination from an extremely small single crystal of a new layered gallium phosphate",

abstract = "A new layered gallium phosphate material [(GaPO4)(4)(OH)F.2(C7H11N2)], DMAP-GaPO, has been prepared using 4-dimethylaminopyridine as a structure directing agent (SDA) in the presence of fluorine. The material consists of layers of a zeolite related fluorinated gallium phosphate separated by the SDA. The structure was solved from single crystal X-ray diffraction data collected from an extremely small crystal using synchrotron radiation. The gallophosphate layer consists of a novel type of secondary building unit (SBU) which is related to the double four ring (D4R) cage, one of the most common motifs in gallium phosphate open framework structures. We propose that this unit could be produced by the isomerisation of a D4R prenucleation building unit (PNBU) on condensation. (C) 2001 Elsevier Science Ltd. All rights reserved.",

keywords = "inorganic compounds, microporous materials, crystal structure, OXYFLUORINATED MICROPOROUS COMPOUNDS, SYNCHROTRON-RADIATION FACILITY, GALLOPHOSPHATE, UNIT",

author = "DS Wragg and Morris, {Russell Edward}",

year = "2001",

month = jul,

language = "English",

volume = "62",

pages = "1493--1497",

journal = "Journal of Physics and Chemistry of Solids",

issn = "0022-3697",

publisher = "Elsevier",

}

RIS (suitable for import to EndNote) - Download

TY - JOUR

T1 - Synthesis and structure determination from an extremely small single crystal of a new layered gallium phosphate

AU - Wragg, DS

AU - Morris, Russell Edward

PY - 2001/7

Y1 - 2001/7

N2 - A new layered gallium phosphate material [(GaPO4)(4)(OH)F.2(C7H11N2)], DMAP-GaPO, has been prepared using 4-dimethylaminopyridine as a structure directing agent (SDA) in the presence of fluorine. The material consists of layers of a zeolite related fluorinated gallium phosphate separated by the SDA. The structure was solved from single crystal X-ray diffraction data collected from an extremely small crystal using synchrotron radiation. The gallophosphate layer consists of a novel type of secondary building unit (SBU) which is related to the double four ring (D4R) cage, one of the most common motifs in gallium phosphate open framework structures. We propose that this unit could be produced by the isomerisation of a D4R prenucleation building unit (PNBU) on condensation. (C) 2001 Elsevier Science Ltd. All rights reserved.

AB - A new layered gallium phosphate material [(GaPO4)(4)(OH)F.2(C7H11N2)], DMAP-GaPO, has been prepared using 4-dimethylaminopyridine as a structure directing agent (SDA) in the presence of fluorine. The material consists of layers of a zeolite related fluorinated gallium phosphate separated by the SDA. The structure was solved from single crystal X-ray diffraction data collected from an extremely small crystal using synchrotron radiation. The gallophosphate layer consists of a novel type of secondary building unit (SBU) which is related to the double four ring (D4R) cage, one of the most common motifs in gallium phosphate open framework structures. We propose that this unit could be produced by the isomerisation of a D4R prenucleation building unit (PNBU) on condensation. (C) 2001 Elsevier Science Ltd. All rights reserved.

KW - inorganic compounds

KW - microporous materials

KW - crystal structure

KW - OXYFLUORINATED MICROPOROUS COMPOUNDS

KW - SYNCHROTRON-RADIATION FACILITY

KW - GALLOPHOSPHATE

KW - UNIT

UR - http://www.scopus.com/inward/record.url?scp=0035427784&partnerID=8YFLogxK

M3 - Article

VL - 62

SP - 1493

EP - 1497

JO - Journal of Physics and Chemistry of Solids

JF - Journal of Physics and Chemistry of Solids

SN - 0022-3697

ER -

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