Skip to content

Research at St Andrews

Synthesis and structure of an unusual new layered aluminophosphate containing oxalate groups, [NH3CH2CH2NH3]2.5[Al4H(HPO4)4(H2PO4)2(C2O4)4]

Research output: Contribution to journalArticlepeer-review

Author(s)

Philip Lightfoot, ZAD Lethbridge, Russell Edward Morris, DS Wragg, Paul Anthony Wright, A Kvick, G Vaughan

School/Research organisations

Abstract

The first example of an aluminophosphate containing organic anions covalently bonded to the framework of the structure is reported; [NH3CH2CH2NH3](2.5)[Al4H(HPO4)(4)(H2PO4)(2)(C2O4)(4)] was prepared hydrothermally and adopts a layered structure. The oxalate groups act as bidentate ligands to Al3+ and hold the structure together by strong interlayer P-O-H-oxalate hydrogen bonds. The structure was solved from synchrotron X-ray diffraction data collected on a very small single crystal, space group C2/m, a = 19.683(4) Angstrom, b = 12.360(3) Angstrom, c = 16.734(3) Angstrom, beta = 110.51(3)degrees. (C) 1999 Academic Press.

Close

Details

Original languageEnglish
Pages (from-to)74
Number of pages74
JournalJournal of Solid State Chemistry
Volume143
Publication statusPublished - 15 Feb 1999

    Research areas

  • MOLECULAR-SIEVES, OPEN-FRAMEWORK

Discover related content
Find related publications, people, projects and more using interactive charts.

View graph of relations

Related by author

  1. Nature of the spin liquid ground state in a breathing kagome compound studied by NMR and series expansion

    Orain, J. C., Bernu, B., Mendels, P., Clark, L., Aidoudi, F. H., Lightfoot, P., Morris, R. E. & Bert, F., 9 Jun 2017, In: Physical Review Letters. 118, 23, 237203.

    Research output: Contribution to journalArticlepeer-review

  2. Extending the family of V4+ S = ½ kagome antiferromagnets

    Clark, L. M., Aidoudi, F. H., Black, C., Athukorala Arachchige, K. S., Slawin, A. M. Z., Morris, R. E. & Lightfoot, P., 14 Dec 2015, In: Angewandte Chemie International Edition. 54, 51, p. 15457-15461 5 p.

    Research output: Contribution to journalArticlepeer-review

  3. Perovskites

    Attfield, J. P., Lightfoot, P. & Morris, R. E., 21 Jun 2015, In: Dalton Transactions. 44, 23, p. 10541-10542 2 p.

    Research output: Contribution to journalEditorialpeer-review

  4. Understanding CO2 adsorption in a flexible zeolite through a combination of structural, kinetic and modelling techniques

    Verbraeken, M. C., Mennitto, R., Georgieva, V. M., Bruce, E. L., Greenaway, A. G., Cox, P. A., Gi Min, J., Bong Hong, S., Wright, P. A. & Brandani, S., 1 Feb 2021, In: Separation and Purification Technology. 256, 14 p., 117846.

    Research output: Contribution to journalArticlepeer-review

  5. Multifaceted study of the interactions between CPO-27-Ni and polyurethane and their impact on nitric oxide release performance

    Vornholt, S. M., Duncan, M. J., Warrender, S. J., Semino, R., Ramsahye, N. A., Maurin, G., Smith, M. W., Tan, J-C., Miller, D. N. & Morris, R. E., 30 Dec 2020, In: ACS Applied Materials & Interfaces. 12, 52, p. 58263-58276

    Research output: Contribution to journalArticlepeer-review

Related by journal

  1. Journal of Solid State Chemistry (Journal)

    Finlay Morrison (Reviewer)

    2010 → …

    Activity: Publication peer-review and editorial work typesPeer review of manuscripts

Related by journal

  1. One pot, three dimensionalities: 1D, 2D and 3D zinc coordination polymers with both N- and O- linkers produced in same reaction

    Carpenter-Warren, C. L. & Slawin, A. M. Z., 1 Jan 2021, In: Journal of Solid State Chemistry. 293, 121717.

    Research output: Contribution to journalArticlepeer-review

  2. Phase transitions in the hexagonal tungsten bronze RbNbW2O9

    McNulty, J. A., Gibbs, A. S., Lightfoot, P. & Morrison, F. D., Jun 2020, In: Journal of Solid State Chemistry. 286, 121275.

    Research output: Contribution to journalArticlepeer-review

  3. Cs7Sm11[TeO3]12Cl16 and Rb7Nd11[TeO3]12Br16, the new tellurite halides of the tetragonal Rb6LiNd11[SeO3]12Cl16 structure type

    Charkin, D. O., Black, C., Downie, L. J., Sklovsky, D. E., Berdonosov, P. S., Olenev, A. V., Zhou, W., Lightfoot, P. & Dolgikh, V. A., Dec 2015, In: Journal of Solid State Chemistry. 232, p. 56-61

    Research output: Contribution to journalArticlepeer-review

  4. Structural, thermal and electrical conductivity characteristics of Ln0.5Sr0.5Ti0.5Mn0.5O3±d (Ln: La, Nd and Sm) complex perovskites as anode materials for solid oxide fuel cell

    Jeong, J., Azad, A. K., Schlegl, H., Kim, B., Baek, S-W., Kim, K., Kang, H. & Kim, J. H., Mar 2015, In: Journal of Solid State Chemistry. 226, p. 154-163 10 p.

    Research output: Contribution to journalArticlepeer-review

ID: 197984

Top