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Synthesis and structure of sterically overloaded tetra-coordinated yttrium and lanthanum disiloxides

Research output: Contribution to journalArticle

Author(s)

Brian McNerney, Suresh Mummadi, Fernando Hung-Low, David B. Cordes, Daniel K. Unruh, Clemens Krempner

School/Research organisations

Abstract

The synthesis, structures and reactivity of the spirocyclic yttrium and lanthanum disiloxides {[(CH2R2SiO)2]2M}H [M = Ln, Y; R = SiMe(SiMe3)2] 3 and 4 are reported. Compounds 3 and 4 were prepared from reactions of two equivalents of [CH2(R)2SiOH]2 [R = Si(SiMe3)2Me] (1) with one equivalent of M[N(SiMe3)2]2 (M = Y, La), respectively.
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Details

Original languageEnglish
Pages (from-to)103-106
Number of pages4
JournalInorganic Chemistry Communications
Volume70
Early online date17 May 2016
DOIs
Publication statusPublished - Aug 2016

    Research areas

  • Siloxide, Silanol, Rare earth siloxide, Yttrium, Lanthanum

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