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Synthesis of homoleptic and heteroleptic bis-N-heterocylic carbene group 11 complexes

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Author(s)

F. Lazreg, D.B. Cordes, A.M.Z. Slawin, C.S.J. Cazin

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Abstract

A straightforward synthetic route has been developed permitting the formation of homoleptic and heteroleptic bis-N-heterocyclic carbene metal complexes. The methodology has proven efficient for all group 11 members. These complexes are easily synthesized using [M(Cl)(NHC)] with different NHC salts in the presence of inexpensive bases such as sodium hydroxide. These systems were fully characterized and displayed high stability even in the presence of light.
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Original languageEnglish
Pages (from-to)419-425
Number of pages7
JournalOrganometallics
Volume34
Issue number2
Early online date8 Jan 2015
DOIs
Publication statusPublished - 26 Jan 2015

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