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Synthesis of zeolites using the ADOR (Assembly-Disassembly-Organization-Reassembly) route

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Synthesis of zeolites using the ADOR (Assembly-Disassembly-Organization-Reassembly) route. / Wheatley, Paul Stewart; Čejka, Jiří; Morris, Russell Edward.

In: Journal of Visualized Experiments, No. 110, e53463, 03.04.2016.

Research output: Contribution to journalArticlepeer-review

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Wheatley, PS, Čejka, J & Morris, RE 2016, 'Synthesis of zeolites using the ADOR (Assembly-Disassembly-Organization-Reassembly) route', Journal of Visualized Experiments, no. 110, e53463. https://doi.org/10.3791/53463

APA

Wheatley, P. S., Čejka, J., & Morris, R. E. (2016). Synthesis of zeolites using the ADOR (Assembly-Disassembly-Organization-Reassembly) route. Journal of Visualized Experiments, (110), [e53463]. https://doi.org/10.3791/53463

Vancouver

Wheatley PS, Čejka J, Morris RE. Synthesis of zeolites using the ADOR (Assembly-Disassembly-Organization-Reassembly) route. Journal of Visualized Experiments. 2016 Apr 3;(110). e53463. https://doi.org/10.3791/53463

Author

Wheatley, Paul Stewart ; Čejka, Jiří ; Morris, Russell Edward. / Synthesis of zeolites using the ADOR (Assembly-Disassembly-Organization-Reassembly) route. In: Journal of Visualized Experiments. 2016 ; No. 110.

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@article{9da3abf9482348baa726a6a6a6f645cd,
title = "Synthesis of zeolites using the ADOR (Assembly-Disassembly-Organization-Reassembly) route",
abstract = "Zeolites are an important class of materials that have wide ranging applications such as heterogeneous catalysts and adsorbents which are dependent on their framework topology. For new applications or improvements to existing ones, new zeolites with novel pore systems are desirable. We demonstrate a method for the synthesis of novel zeolites using the ADOR route. ADOR is an acronym for Assembly, Disassembly, Organization and Reassembly. This synthetic route takes advantage of the assembly of a relatively poorly stable zeolite which can be selectively disassembled into a layered material. The resulting layered intermediate can then be organized in different manners by careful chemical manipulation and then reassembled into zeolites with new topologies. By carefully controlling the organization step of the synthetic pathway, new zeolites with never before seen topologies are capable of being synthesized. The structures of these new zeolites are confirmed using powder X-ray diffraction and further characterized by nitrogen adsorption and scanning electron microscopy. This new synthetic pathway for zeolites demonstrates its capability to produce novel frameworks that have never been prepared by traditional zeolite synthesis techniques.",
keywords = "Zeolites, Synthesis, ADOR mechanism, Porosity, Germanosilicate, Silica",
author = "Wheatley, {Paul Stewart} and Ji{\v r}{\'i} {\v C}ejka and Morris, {Russell Edward}",
note = "R.E.M. thanks the Royal Society and the E.P.S.R.C. (Grants EP/L014475/1, EP/K025112/1 and EP/K005499/1) for funding work in this area. J.{\v C}. acknowledges the Czech Science Foundation for the project of the Centre of Excellence (P106/12/G015) and the European Union Seventh Framework Programme (FP7/ 2007-‐‐2013) under grant agreement n°604307.",
year = "2016",
month = apr,
day = "3",
doi = "10.3791/53463",
language = "English",
journal = "Journal of Visualized Experiments",
issn = "1940-087X",
publisher = "MYJoVE Corporation",
number = "110",

}

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TY - JOUR

T1 - Synthesis of zeolites using the ADOR (Assembly-Disassembly-Organization-Reassembly) route

AU - Wheatley, Paul Stewart

AU - Čejka, Jiří

AU - Morris, Russell Edward

N1 - R.E.M. thanks the Royal Society and the E.P.S.R.C. (Grants EP/L014475/1, EP/K025112/1 and EP/K005499/1) for funding work in this area. J.Č. acknowledges the Czech Science Foundation for the project of the Centre of Excellence (P106/12/G015) and the European Union Seventh Framework Programme (FP7/ 2007-‐‐2013) under grant agreement n°604307.

PY - 2016/4/3

Y1 - 2016/4/3

N2 - Zeolites are an important class of materials that have wide ranging applications such as heterogeneous catalysts and adsorbents which are dependent on their framework topology. For new applications or improvements to existing ones, new zeolites with novel pore systems are desirable. We demonstrate a method for the synthesis of novel zeolites using the ADOR route. ADOR is an acronym for Assembly, Disassembly, Organization and Reassembly. This synthetic route takes advantage of the assembly of a relatively poorly stable zeolite which can be selectively disassembled into a layered material. The resulting layered intermediate can then be organized in different manners by careful chemical manipulation and then reassembled into zeolites with new topologies. By carefully controlling the organization step of the synthetic pathway, new zeolites with never before seen topologies are capable of being synthesized. The structures of these new zeolites are confirmed using powder X-ray diffraction and further characterized by nitrogen adsorption and scanning electron microscopy. This new synthetic pathway for zeolites demonstrates its capability to produce novel frameworks that have never been prepared by traditional zeolite synthesis techniques.

AB - Zeolites are an important class of materials that have wide ranging applications such as heterogeneous catalysts and adsorbents which are dependent on their framework topology. For new applications or improvements to existing ones, new zeolites with novel pore systems are desirable. We demonstrate a method for the synthesis of novel zeolites using the ADOR route. ADOR is an acronym for Assembly, Disassembly, Organization and Reassembly. This synthetic route takes advantage of the assembly of a relatively poorly stable zeolite which can be selectively disassembled into a layered material. The resulting layered intermediate can then be organized in different manners by careful chemical manipulation and then reassembled into zeolites with new topologies. By carefully controlling the organization step of the synthetic pathway, new zeolites with never before seen topologies are capable of being synthesized. The structures of these new zeolites are confirmed using powder X-ray diffraction and further characterized by nitrogen adsorption and scanning electron microscopy. This new synthetic pathway for zeolites demonstrates its capability to produce novel frameworks that have never been prepared by traditional zeolite synthesis techniques.

KW - Zeolites

KW - Synthesis

KW - ADOR mechanism

KW - Porosity

KW - Germanosilicate

KW - Silica

U2 - 10.3791/53463

DO - 10.3791/53463

M3 - Article

JO - Journal of Visualized Experiments

JF - Journal of Visualized Experiments

SN - 1940-087X

IS - 110

M1 - e53463

ER -

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