Skip to content

Research at St Andrews

Synthetic and crystallographic investigation of the layered coordination framework copper-1,3-bis(4-carboxyphenyl)-5-ethoxybenzene

Research output: Contribution to journalArticlepeer-review

DOI

Author(s)

Lauren N. McHugh, David B. Cordes, Paul S. Wheatley, Alexandra M. Z. Slawin, Russell E. Morris

School/Research organisations

Abstract

The reaction of 1,3-bis(4-carboxyphenyl)-5-ethoxybenzene and copper acetate monohydrate yields copper-1,3-bis(4-carboxyphenyl)-5-ethoxybenzene(DMF), and upon removal of coordinated DMF molecules, copper-1,3-bis(4-carboxyphenyl)-5-ethoxybenzene is attained. The compound does not form as a traditional three-dimensional metal–organic framework and instead produces a “layered coordination framework”, where the individual layers are separated by the ethyl chains on the linker. The synthesis and crystallographic characterization of the material are described.
Close

Details

Original languageEnglish
Pages (from-to)39-42
Number of pages4
JournalCrystal Growth & Design
Volume20
Issue number1
Early online date2 Dec 2019
DOIs
Publication statusPublished - 2 Jan 2020

Discover related content
Find related publications, people, projects and more using interactive charts.

View graph of relations

Related by author

  1. Preventing undesirable structure flexibility in pyromellitate metal organic frameworks

    Hayes, O. G., Warrender, S. J., Cordes, D. B., Duncan, M. J., Slawin, A. M. Z. & Morris, R. E., 15 Jul 2020, In: European Journal of Inorganic Chemistry. 2020, 26, p. 2537-2544 8 p.

    Research output: Contribution to journalArticlepeer-review

  2. Conversion of a microwave synthesized alkali-metal MOF to carbonaceous anode for Li-ion batteries

    Desai, A. V., Pereira Pimenta, V. J., King, C., Cordes, D. B., Slawin, A. M. Z., Morris, R. E. & Armstrong, R., 2020, In: RSC Advances. 10, 23, p. 13732-13736

    Research output: Contribution to journalArticlepeer-review

  3. Synthesis and structural characterisation of the copper MOF: STAM-NMe2

    McHugh, L. N., Olivera Perez, L., Wheatley, P. S., Cordes, D. B., Slawin, A. M. Z. & Morris, R. E., 28 Sep 2019, In: CrystEngComm. 21, 36, p. 5387-5391

    Research output: Contribution to journalArticlepeer-review

  4. A single crystal study of CPO-27 and UTSA-74 for nitric oxide storage and release

    Henkelis, S. E., Vornholt, S. M., Cordes, D. B., Slawin, A. M. Z., Wheatley, P. S. & Morris, R. E., 28 Mar 2019, In: CrystEngComm. 21, 12, p. 1857-1861

    Research output: Contribution to journalArticlepeer-review

  5. Crystal structure resolution of two different chlorhexidine salts

    Cattaneo, D., McCormick, L. J., Cordes, D. B., Slawin, A. M. Z. & Morris, R. E., 5 Oct 2016, In: Journal of Molecular Structure. 1121, p. 70-73 4 p.

    Research output: Contribution to journalArticlepeer-review

Related by journal

  1. Naturally occurring and biomimetic synthesized calcite spherulites

    Wu, S., Blake, J., Guo, L. & Zhou, W., 17 Apr 2020, In: Crystal Growth & Design. In press

    Research output: Contribution to journalArticlepeer-review

  2. Reversible, two-step single-crystal to single-crystal phase transitions between desloratadine forms I, II, and III

    Srirambhatla, V. K., Guo, R., Dawson, D. M., Price, S. L. & Florence, A. J., 28 Jan 2020, In: Crystal Growth & Design. Articles ASAP, 11 p.

    Research output: Contribution to journalArticlepeer-review

  3. Enhancement of electrical conductivity due to structural distortion from linear to nonlinear dicarboxylato-bridged Zn(II) 1D-coordination polymers

    Naskar, K., Sil, S., Sahu, N., Dutta, B., Slawin, A. M. Z., Ray, P. P. & Sinha, C., 1 May 2019, In: Crystal Growth & Design. 19, 5, p. 2632-2641 10 p.

    Research output: Contribution to journalArticlepeer-review

  4. Evolution of anodic product from molybdenum metal in absolute ethanol and humidity sensing under ambient conditions

    Ni, C., Carolan, D., Hui, J., Rocks, C., Padmanaban, D., Ni, J., Xie, D., Fang, Z., Irvine, J., Maguire, P. & Mariotti, D., 4 Sep 2019, In: Crystal Growth & Design. 19, 9, p. 5249-5257 9 p.

    Research output: Contribution to journalArticlepeer-review

ID: 266096008

Top