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Synthetic control of framework zinc purinate crystallisation and properties of a large pore, decorated, mixed-linker RHO-type ZIF

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Author(s)

Juergen Kahr, John P. S. Mowat, Alexandra M. Z. Slawin, Russell E. Morris, David Fairen-Jimenez, Paul A. Wright

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Abstract

A novel form of mixed-linker ZIF with the RHO topology is one of four zinc-imidazolate frameworks prepared with purine and 2-nitroimidazole. In this structure the linkers order to give a large pore solid with a high pore volume and an unusual symmetry and linker orientation. It possesses extra-framework zinc imidazolate units decorating the internal surface which can be removed to give high porosity.

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Details

Original languageEnglish
Pages (from-to)6690-6692
Number of pages3
JournalChemical Communications
Volume48
Issue number53
DOIs
Publication statusPublished - 2012

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