Skip to content

Research at St Andrews

The Assembly-Disassembly-Organization-Reassembly mechanism for 3D-2D-3D transformation of germanosilicate IWW zeolite

Research output: Contribution to journalArticle

Author(s)

Pavla Chlubná-Eliášová, Yuyang Tian, Ana B. Pinar, Martin Kubů, Jiří Čejka, Russell Edward Morris

School/Research organisations

Abstract

Hydrolysis of germanosilicate zeolites with the IWW structure shows two different outcomes depending on the composition of the starting materials. Ge-rich IWW (Si/Ge=3.1) is disassembled into a layered material (IPC-5P), which can be reassembled into an almost pure silica IWW on treatment with diethoxydimethylsilane. Ge-poor IWW (Si/Ge=6.4) is not completely disassembled on hydrolysis, but retains some 3D connectivity. This structure can be reassembled into IWW by incorporation of Al to fill the defects left when the Ge is removed.
Close

Details

Original languageEnglish
Pages (from-to)7168–7172
JournalAngewandte Chemie
Volume126
Issue number27
Early online date13 May 2014
DOIs
Publication statusPublished - 1 Jul 2014

    Research areas

  • ADOR, Festkörperreaktionen, Germanosilicate, IWW, Zeolithe

Discover related content
Find related publications, people, projects and more using interactive charts.

View graph of relations

Related by author

  1. Sodium naphthalene-2,6-dicarboxylate: an anode for sodium batteries

    Cabañero, J. M., Pereira Pimenta, V., Cannon, K., Morris, R. & Armstrong, A. R., 7 Aug 2019, (Accepted/In press) In : CHEMSUSCHEM. In press

    Research output: Contribution to journalArticle

  2. Metal-organic framework-activated carbon composite materials for the removal of ammonia from contaminated airstreams

    McHugh, L. N., Terracina, A., Wheatley, P. S., Buscarino, G., Smith, M. W. & Morris, R. E., 17 Jul 2019, In : Angewandte Chemie International Edition. Early View

    Research output: Contribution to journalArticle

  3. Magneto-structural correlations of novel kagomé-type metal organic frameworks

    H. Mohideen, M. I., Lei, C., Tuček, J., Malina, O., Brivio, F., Kasneryk, V., Huang, Z., Mazur, M., Zou, X., Nachtigall, P., Čejka, J. & Morris, R. E., 14 Jun 2019, In : Journal of Materials Chemistry. 7, 22, p. 6692-6697 6 p.

    Research output: Contribution to journalArticle

  4. Nitric oxide production from nitrite by a series of zeolites produced via the ADOR route

    Doyle, R. A., Russell, S. E. & Morris, R. E., 15 May 2019, In : Microporous and Mesoporous Materials. 280, p. 367-371 5 p.

    Research output: Contribution to journalArticle

  5. 13C pNMR of “crumple zone” Cu(II) isophthalate metal-organic frameworks

    Dawson, D. M., Sansome, C. E. F., McHugh, L. N., McPherson, M. J., McCormick McPherson, L. J., Morris, R. E. & Ashbrook, S. E., 14 May 2019, In : Solid State Nuclear Magnetic Resonance. In press

    Research output: Contribution to journalArticle

Related by journal

  1. Angewandte Chemie (Journal)

    J Derek Woollins (Editor)
    2005 → …

    Activity: Publication peer-review and editorial work typesEditor of research journal

Related by journal

  1. Sub-micromolar pulse dipolar EPR spectroscopy reveals increasing CuII-labelling of double-histidine motifs with lower temperature

    Wort, J., Ackermann, K., Giannoulis, A., Stewart, A. J., Norman, D. & Bode, B. E., 18 Jul 2019, In : Angewandte Chemie. 131, 34, p. 11807-11811 6 p.

    Research output: Contribution to journalArticle

  2. A highly active manganese catalyst for enantioselective ketone and ester hydrogenation

    Widegren, M. B., Harkness, G. J., Slawin, A. M. Z., Cordes, D. B. & Clarke, M. L., 15 May 2017, In : Angewandte Chemie. 129, 21, p. 5919-5922 4 p.

    Research output: Contribution to journalArticle

  3. Enzyme activity by design: an artificial rhodium hydroformylase for linear aldehydes

    Jarvis, A., Obrecht, L., Deuss, P., Laan, W., Gibson, E. K., Wells, P. P. & Kamer, P. C. J., 23 Oct 2017, In : Angewandte Chemie. 129, 44, p. 13784-13788

    Research output: Contribution to journalArticle

  4. Expansion of the ADOR strategy for the synthesis of new zeolites: the synthesis of IPC-12 from zeolite UOV

    Kasneryk, V., Shamzhy, M., Opanasenko, M., Wheatley, P. S., Morris, S. A., Russell, S. E., Mayoral, A., Trachta, M., Čejka, J. & Morris, R. E., 3 Apr 2017, In : Angewandte Chemie. 56, 15, p. 4324-4327 5 p.

    Research output: Contribution to journalArticle

  5. Enzymatic macrocyclization of 1,2,3-triazole peptide mimetics

    Oueis, E., Jaspars, M., Westwood, N. J. & Naismith, J., 4 May 2016, In : Angewandte Chemie. 55, 19, p. 5842-5845

    Research output: Contribution to journalArticle

ID: 118403513