Skip to content

Research at St Andrews

The location of fluoride and organic guests in 'as-made' pure silica zeolites FER and CHA

Research output: Contribution to journalArticle

DOI

Author(s)

Luis A Villaescusa, Ivor Bull, Paul S Wheatley, Philip Lightfoot, Russell Edward Morris

School/Research organisations

Abstract

The structure determination of as-made silica zeolites CHA and FER prepared in the presence of fluoride ions has been accomplished using microcrystal X-ray diffraction at a synchrotron source. In both cases, the location of the fluoride ions has been determined. Fluoride ions are incorporated into small double six-ring cages in the CHA framework, and the organic guests have been located in the larger chabazite cages. In contrast to two previous single-crystal X-ray diffraction studies of as-made siliceous FER prepared in related ways fluoride ions are incorporated into the framework and are found occluded inside small cages in the structure.

Close

Details

Original languageEnglish
Pages (from-to)1978-1982
Number of pages5
JournalJournal of Materials Chemistry
Volume13
DOIs
Publication statusPublished - 2003

    Research areas

  • X-RAY-DIFFRACTION, SOLID-STATE NMR, SI-29 MAS-NMR, 5-COORDINATE SILICON, MOLECULAR-SIEVES, BETA-ZEOLITE, FERRIERITE, FRAMEWORK, TEMPLATE, IONS

Discover related content
Find related publications, people, projects and more using interactive charts.

View graph of relations

Related by author

  1. Nature of the spin liquid ground state in a breathing kagome compound studied by NMR and series expansion

    Orain, J. C., Bernu, B., Mendels, P., Clark, L., Aidoudi, F. H., Lightfoot, P., Morris, R. E. & Bert, F., 9 Jun 2017, In : Physical Review Letters. 118, 23, 237203.

    Research output: Contribution to journalArticle

  2. Extending the family of V4+ S = ½ kagome antiferromagnets

    Clark, L. M., Aidoudi, F. H., Black, C., Athukorala Arachchige, K. S., Slawin, A. M. Z., Morris, R. E. & Lightfoot, P., 14 Dec 2015, In : Angewandte Chemie International Edition. 54, 51, p. 15457-15461 5 p.

    Research output: Contribution to journalArticle

  3. Perovskites

    Attfield, J. P., Lightfoot, P. & Morris, R. E., 21 Jun 2015, In : Dalton Transactions. 44, 23, p. 10541-10542 2 p.

    Research output: Contribution to journalEditorial

  4. μsR study of a quantum spin liquid candidate: The S=1/2 vanadium oxyfluoride kagome antiferromagnet

    Orain, J. C., Clark, L., Bert, F., Mendels, P., Attfield, P., Aidoudi, F. H., Morris, R. E., Lightfoot, P., Amato, A. & Baines, C., 1 Jan 2014, J. Phys. Conf. Ser.. 1 ed. Vol. 551. (Journal of Physics: Conference Series).

    Research output: Chapter in Book/Report/Conference proceedingConference contribution

  5. Structural diversity in hybrid vanadium(IV) oxyfluorides based on a common building block

    Aidoudi, F. H., Black, C., Arachchige, K. S. A., Slawin, A. M. Z., Morris, R. E. & Lightfoot, P., 2014, In : Dalton Transactions. 43, 2, p. 568-575 8 p.

    Research output: Contribution to journalArticle

Related by journal

  1. Journal of Materials Chemistry (Journal)

    Finlay Morrison (Reviewer)
    2008 → …

    Activity: Publication peer-review and editorial work typesPeer review of manuscripts

  2. Journal of Materials Chemistry (Journal)

    John Thomas Sirr Irvine (Member of editorial board)
    2007 → …

    Activity: Publication peer-review and editorial work typesEditor of research journal

Related by journal

  1. B-site doped perovskite ferrate for efficient anode of a solid oxide fuel cell with in situ metal exsolution

    Ni, C., Zeng, Q., He, D., Peng, L., Xie, D-T., Irvine, J., Duan, S. & Ni, J-P., 29 Oct 2019, In : Journal of Materials Chemistry. In press

    Research output: Contribution to journalArticle

  2. Hexagonal perovskite related oxide ion conductor Ba3NbMoO8.5: phase transition, temperature evolution of the local structure and properties

    Chambers, M. S., McCombie, K. S., Auckett, J. E., McLaughlin, A. C., Irvine, J. T. S., Chater, P. A., Evans, J. S. O. & Evans, I. R., 28 Nov 2019, In : Journal of Materials Chemistry. 7, 44, p. 25503-25510 8 p.

    Research output: Contribution to journalArticle

  3. Magneto-structural correlations of novel kagomé-type metal organic frameworks

    H. Mohideen, M. I., Lei, C., Tuček, J., Malina, O., Brivio, F., Kasneryk, V., Huang, Z., Mazur, M., Zou, X., Nachtigall, P., Čejka, J. & Morris, R. E., 14 Jun 2019, In : Journal of Materials Chemistry. 7, 22, p. 6692-6697 6 p.

    Research output: Contribution to journalArticle

  4. Revealing resonance effects and intramolecular dipole interactions in the positional isomers of benzonitrile-core thermally activated delayed fluorescence materials

    Kukhta, N. A., Higginbotham, H. F., Matulaitis, T., Danos, A., Bismillah, A. N., Haase, N., Etherington, M. K., Yufit, D. S., McGonigal, P. R., Gražulevičius, J. V. & Monkman, A. P., 14 Aug 2019, In : Journal of Materials Chemistry. 7, 30, p. 9184-9194 11 p.

    Research output: Contribution to journalArticle

  5. STA-27, a porous Lewis acidic scandium MOF with an unexpected topology type prepared with 2,3,5,6-tetrakis(4-carboxyphenyl)pyrazine

    Prasad, R., Seidner, S., Cordes, D. B., Lozinska, M., Dawson, D., Thompson, M., Düren, T., Chakarova, K., Mihaylov, M., Hadjiivanov, K., Hoffmann, F., Slawin, A. M. Z., Ashbrook, S. E., Clarke, M. & Wright, P., 14 Mar 2019, In : Journal of Materials Chemistry. 7, 10, p. 5685-5701

    Research output: Contribution to journalArticle

ID: 233378

Top