Skip to content

Research at St Andrews

The role of added water in the ionothermal synthesis of microporous aluminium phosphates

Research output: Contribution to journalArticle

Author(s)

School/Research organisations

Abstract

Water plays an important role in ionothermal synthesis and it has been suggested that it can influence phase selection. We have carried out an extensive study to determine the phases produced at various ratios of water to ionic liquid in the microwave assisted ionothermal synthesis of fluorinated aluminium phosphate frameworks using 1-ethyl-3-methylimidazolium bromide and 1-ethylpyridinium bromide. Aluminophosphate chabazite is the main product under ionothermal conditions while at increased levels of water the ionic liquids appear to be poor templates with dense phases predominating. The low synthesis pressure in ionothermal reactions is demonstrated and the role of template breakdown in phase selection is also discussed. (C) 2008 Elsevier Masson SAS. All rights reserved.

Close

Details

Original languageEnglish
Pages (from-to)411-416
Number of pages6
JournalSolid State Sciences
Volume11
Issue number2
DOIs
Publication statusPublished - Feb 2009

    Research areas

  • Ionothermal synthesis, Microwave, High throughput, X-ray diffraction, Aluminium phosphates, HIGH-THROUGHPUT SYNTHESIS, METAL-ORGANIC FRAMEWORKS, MOLECULAR-SIEVES, IONIC-LIQUID, INORGANIC MATERIALS, MICROWAVE SYNTHESIS, ZEOLITE, ALUMINOPHOSPHATE, SOLVENTS, SODALITE

Discover related content
Find related publications, people, projects and more using interactive charts.

View graph of relations

Related by author

  1. A single crystal study of CPO-27 and UTSA-74 for nitric oxide storage and release

    Henkelis, S. E., Vornholt, S. M., Cordes, D. B., Slawin, A. M. Z., Wheatley, P. S. & Morris, R. E., 28 Mar 2019, In : CrystEngComm. 21, 12, p. 1857-1861

    Research output: Contribution to journalArticle

  2. Solvent dependent disorder in M2(BzOip)2(H2O)·solvate (M = Co or Zn)

    McCormick, L. J., Morris, S. A., Teat, S. J., Slawin, A. M. Z. & Morris, R. E., 24 Dec 2017, In : Crystals. 8, 1

    Research output: Contribution to journalArticle

  3. Assembly-diassembly-organization-reassembly synthesis of zeolites based on cfi-type layers

    Firth, D. S., Morris, S. A., Wheatley, P. S., Russell, S. E., Slawin, A. M. Z., Dawson, D. M., Mayoral, A., Opanasenko, M., Položij, M., Čejka, J., Nachtigall, P. & Morris, R. E., 11 Jul 2017, In : Chemistry of Materials. 29, 13, p. 5605-5611

    Research output: Contribution to journalArticle

  4. Crystal structure resolution of two different chlorhexidine salts

    Cattaneo, D., McCormick, L. J., Cordes, D. B., Slawin, A. M. Z. & Morris, R. E., 5 Oct 2016, In : Journal of Molecular Structure. 1121, p. 70-73 4 p.

    Research output: Contribution to journalArticle

  5. Coordination polymers of 5-alkoxy isophthalic acids

    McCormick, L. J., Morris, S. A., Slawin, A. M. Z., Teat, S. J. & Morris, R. E., 5 Oct 2016, In : Crystal Growth & Design. 16, 10, p. 5771-5780 10 p.

    Research output: Contribution to journalArticle

Related by journal

  1. Conductivity and redox stability of perovskite oxide SrFe1-xTixO3-delta (x

    Cowin, P. I., Lan, R., Petit, C. T. G. & Tao, S., Aug 2015, In : Solid State Sciences. 46, p. 62-70 9 p.

    Research output: Contribution to journalArticle

  2. Structure and conductivity of praseodymium and yttrium co-doped barium cerates

    Petit, C. T. G. & Tao, S., Mar 2013, In : Solid State Sciences. 17, p. 115-121 7 p.

    Research output: Contribution to journalArticle

  3. Crystallographic, magnetic and dielectric studies of the potential multiferroic cryolite (NH4)3FeF6

    Goff, R. J., Tang, C. C., Parker, J. E., Morrison, F. D. & Lightfoot, P., May 2011, In : Solid State Sciences. 13, 5, p. 953-958 6 p.

    Research output: Contribution to journalArticle

  4. Fluoroaluminates of purine and DNA bases, adenine, guanine: [Hpur](2)center dot(AlF5), [Hade](3)center dot(AlF6)center dot 6.5H(2)O, [Hguan](3)center dot(Al3F12)

    Cadiau, A., Adil, K., Hemon-Ribaud, A., Leblanc, M., Jouanneaux, A., Slawin, A. M. Z., Lightfoot, P. & Maisonneuve, V., Jan 2011, In : Solid State Sciences. 13, 1, p. 151-157 7 p.

    Research output: Contribution to journalArticle

  5. The ionothermal synthesis of metal organic frameworks, Ln(C9O6H3) ((CH3NH)2CO)2 , using deep eutectic solvents

    Himeur, F. H., Stein, I., Wragg, D. S., Slawin, A. M. Z., Lightfoot, P. & Morris, R. E., Apr 2010, In : Solid State Sciences. 12, 4, p. 418-421 4 p.

    Research output: Contribution to journalArticle

ID: 16815399

Top