Research output: Contribution to journal › Article › peer-review
Gesley A. V. Martins, Peter Joseph Byrne, Phoebe Allan, Simon J. Teat, Alexandra Martha Zoya Slawin, Yang Li, Russell Edward Morris
Four zinc imidazolate materials has been synthesized under ionothermal conditions using ionic liquids; [Zn(C2O4)(C3N2H4)], P2(1)/a (1); [Zn(CH3COO)(C3N2H3)], Ima2 (2); [Zn-4(C3N2H4)(C3N2H3)(8)], P (1) over bar1 (3) and [Zn(C3N2H3)(2)], I4(1) (4). Compounds 1 and 4 have already known structures, but have been synthesised for the first time using ionothermal methods. Compounds 2 and 3 are novel and have been synthesized for the first time in this work. The syntheses of 3 and 4 take place under almost exactly the same conditions, except that a lower synthesis temperature leads to a proportion of terminal imidazolate units in the structure of 3 while a slightly higher temperature leads to all bridging imidazolate units in 4.
Original language | English |
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Pages (from-to) | 1758-1762 |
Number of pages | 5 |
Journal | Dalton Transactions |
Volume | 39 |
Issue number | 7 |
Early online date | 22 Dec 2009 |
DOIs | |
Publication status | Published - 21 Feb 2010 |
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Research output: Contribution to journal › Article › peer-review
Research output: Contribution to journal › Article › peer-review
Research output: Contribution to journal › Article › peer-review
Research output: Contribution to journal › Article › peer-review
Research output: Contribution to journal › Article › peer-review
Finlay Morrison (Reviewer)
Activity: Publication peer-review and editorial work types › Peer review of manuscripts
Research output: Contribution to journal › Article › peer-review
Research output: Contribution to journal › Article › peer-review
Research output: Contribution to journal › Article › peer-review
Research output: Contribution to journal › Article › peer-review
Research output: Contribution to journal › Article › peer-review
ID: 16812932