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Thionylimido complexes

Research output: Contribution to journalArticlepeer-review

Author(s)

Liam J. R. McGeachie, Cameron L. Carpenter-Warren, David B. Cordes, Michael Buehl, Steven J. Gray, Guoxiong Hua, Alexandra M. Z. Slawin, J Derek Woollins

School/Research organisations

Abstract

An improved route to d-block and main group NSO complexes is presented including the synthesis of the first antimony(V) complexes, (Ar3Sb(NSO)2), and copper examples (CuBipy(PPh3)NSO). The structures of eight complexes are reported. The observed variation in M-N-S bond angles is due to the combination of orbital overlap (ligand-to-metal bonding) and the degree of ionicity of the bonding.
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Details

Original languageEnglish
Pages (from-to)1795-1798
Number of pages5
JournalZeitschrift für Anorganische und Allgemeine Chemie
Volume646
Issue number22
Early online date12 Aug 2020
DOIs
Publication statusPublished - 27 Nov 2020

    Research areas

  • Thionylimide, Thiazate, Complex, Antimony, X-ray structure

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