Skip to content

Research at St Andrews

Thiophene -2-carbonyl azide

Research output: Contribution to journalArticlepeer-review

Author(s)

Gene C. Hsu, Laci M. Singer, David B. Cordes, Michael Findlater

School/Research organisations

Abstract

The title compound, C5H3N3OS, is almost planar (r.m.s. deviation for the ten non-H atoms = 0.018 Å) and forms an extended layer structure in the (100) plane, held together via hydrogen-bonding interactions between adjacent molecules. Of particular note is the occurrence of RC—H···N-=N+=NR interactions between an aromatic C—H group and an azide moiety which, in conjunction with a
complementary C—H···O=C interaction, forms a nine-membered ring.

Close

Details

Original languageEnglish
Pages (from-to)o1298
Number of pages1
JournalActa Crystallographica. Section E, Structure reports online
Volume69
Issue number8
DOIs
Publication statusPublished - Aug 2013

Discover related content
Find related publications, people, projects and more using interactive charts.

View graph of relations

Related by author

  1. Janus all-cis 2,3,4,5,6-pentafluorocyclohexyl building blocks applied to medicinal chemistry and bioactives discovery chemistry

    O'Hagan, D., Clark, J., Neyyappadath, R. M., Yu, C., Slawin, A. M. Z. & Cordes, D. B., 6 Sep 2021, (Accepted/In press) In: Chemistry - A European Journal. In press

    Research output: Contribution to journalArticlepeer-review

  2. New variants of (110)-oriented layered lead bromide perovskites, templated by formamidinium or pyrazolium

    Guo, Y., Elliott, C., McNulty, J., Cordes, D., Slawin, A. & Lightfoot, P., 12 Aug 2021, (E-pub ahead of print) In: European Journal of Inorganic Chemistry. Early View

    Research output: Contribution to journalArticlepeer-review

  3. Structural diversity in hybrid lead halides templated by 4-methylimidazolium

    Elliott, C., McNulty, J. A., Cordes, D. B., Slawin, A. M. Z. & Lightfoot, P., 2 Aug 2021, (E-pub ahead of print) In: Journal of Solid State Chemistry. In press, 122466.

    Research output: Contribution to journalArticlepeer-review

  4. Substitution effects on a new pyridylbenzimidazole acceptor for thermally activated delayed fluorescence and their use in organic light-emitting diodes

    Hall, D., Rajamalli, P., Duda, E., Madayanad Suresh, S., Rodella, F., Bagnich, S., Carpenter-Warren, C. L., Cordes, D. B., Slawin, A. M. Z., Strohriegl, P., Beljonne, D., Köhler, A., Olivier, Y. & Zysman-Colman, E., 2 Aug 2021, (E-pub ahead of print) In: Advanced Optical Materials. Early View, 13 p., 2100846.

    Research output: Contribution to journalArticlepeer-review

  5. A luminescent 1D silver polymer containing [2.2]paracyclophane ligands

    Mackenzie, C. F. R., Delforce, L., Rota Martir, D., Cordes, D. B., Slawin, A. M. Z. & Zysman-Colman, E., 2 Aug 2021, In: Frontiers in Chemistry. 9, 6 p., 728845.

    Research output: Contribution to journalArticlepeer-review

Related by journal

  1. Crystal structures of 2,2′-bipyridin-1-ium 1,1,3,3-tetracyano-2-ethoxyprop-2-en-1-ide and bis(2,2′-bipyridin-1-ium) 1,1,3,3-tetracyano-2-(dicyano-methylene) propane-1,3-diide

    Setifi, Z., Valkonen, A., Fernandes, M. A., Nummelin, S., Boughzala, H., Setifi, F., Glidewell, C. & Harrison, W. T. A., May 2015, In: Acta Crystallographica. Section E, Structure reports online. 71, 5, p. 509-515 7 p.

    Research output: Contribution to journalArticlepeer-review

  2. The crystal structures of three clozapinium salts: different molecular configurations, and supramolecular assembly in one, two and three dimensions

    Kaur, M., Jasinski, J. P., Yathirajan, H. S., Kavitha, C. N., Glidewell, C. & Harrison, W. T. A., Apr 2015, In: Acta Crystallographica. Section E, Structure reports online. 71, 4, p. 406-413 8 p.

    Research output: Contribution to journalArticlepeer-review

  3. Crystal structure of 3-benzoyl-2-[(5-bromo-2-Hydroxy-3-methoxybenzylidene)amino]-4,5,6,7-tetrahydrobenzo[b]thiophene

    Kaur, M., Jasinski, J. P., Yathirajan, H. S., Glidewell, C., Byrappa, K. & Stoeckli-Evans, H., Feb 2015, In: Acta Crystallographica. Section E, Structure reports online. 71, 2, p. 176-179 4 p.

    Research output: Contribution to journalArticlepeer-review

  4. tert-Butyl N-(thiophen-2-yl)carbamate

    Hsu, G. C., Singer, L. M., Cordes, D. B. & Findlater, M., Sep 2013, In: Acta Crystallographica. Section E, Structure reports online. 69, 9, p. o1413 1 p.

    Research output: Contribution to journalArticlepeer-review

ID: 66477663

Top