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Three-layer π-stacking in a dinuclear Cd(NO3)2 complex formed from a new four-armed thiopyridine ligand

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Author(s)

David B. Cordes, Lyall R. Hanton

School/Research organisations

Abstract

The flexible four-armed ligand 1,2,4,5-tetrakis(2-pyridylmethylsulfanylmethyl)benzene (2tet) was synthesized and reacted with
Cd(NO3)2 to produce a dinuclear complex. The ligand adopted a folded conformation about the seven and eight coordinate Cd(II)
centres and displayed an intramolecular three-layered p-stacking arrangement.

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Details

Original languageEnglish
Pages (from-to)967-970
Number of pages4
JournalInorganic Chemistry Communications
Volume8
Early online date8 Sep 2005
DOIs
Publication statusPublished - Sep 2005

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