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Tilting and twisting in a novel perovzalate, K3NaMn(C2O4)3

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Author(s)

Xiaolong He, Xinyuan Zhang, Bifa Ji, Wenjiao Yao, Philip Lightfoot, Yongbing Tang

School/Research organisations

Abstract

In the title compound, the oxalate ligand simultaneously bridges both Mn-centred and Na-centred octahedra to produce a unique ‘doubly-interpenetrated’ perovskite-like lattice with an unconventional octahedral tilt system. In turn, the coordination requirements of the oxalate ligand lead to a rare ‘twisted’ conformation.
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Original languageEnglish
Pages (from-to)2567-2570
JournalChemical Communications
Volume57
Issue number20
Early online date4 Feb 2021
DOIs
Publication statusE-pub ahead of print - 4 Feb 2021

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