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Understanding the adsorption mechanism of noble gases Kr and Xe in CPO-27-Ni, CPO-27-Mg, and ZIF-8

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Author(s)

O V Magdysyuk, F Adams, H-P Liermann, I Spanopoulos, P N Trikalitis, M Hirscher, R E Morris, M J Duncan, L J McCormick, R E Dinnebier

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Abstract

An experimental study of Xe and Kr adsorption in metal-organic frameworks CPO-27-Ni, CPO-27-Mg, and ZIF-8 was carried out. In situ synchrotron X-ray powder diffraction experiments allowed precise determination of the adsorption sites and sequence of their filling with increasing of gas pressure at different temperatures. Structural investigations were used for interpretation of gas adsorption measurements.
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Original languageEnglish
Pages (from-to)23908-23914
Number of pages7
JournalPhysical Chemistry Chemical Physics
Volume16
Issue number43
Early online date17 Sep 2014
DOIs
Publication statusPublished - 21 Nov 2014

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