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Variable dimensionality in 'hollow' hybrid tin iodide perovskites

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Abstract

Two ‘hollow’ B-site deficient perovskites, (TzH)11(H3PO2)Sn6I23 and (TzH)3Sn2I7 (TzH+ = 1,2,4-triazolium, H3PO2 = hypohosphorous acid), have been prepared. (TzH)11(H3PO2)Sn6I23 is the first example of a 2D layered structure of this type. Leaving the same reaction mixture for an extended time also affords the 3D derivative (TzH)3Sn2I7.
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Original languageEnglish
JournalDalton Transactions
VolumeAdvance Articles
Early online date26 Oct 2020
DOIs
Publication statusE-pub ahead of print - 26 Oct 2020

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