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Variable temperature high resolution 29Si MAS NMR of siliceous zeolite ferrierite

Research output: Contribution to journalArticle

DOI

Author(s)

RJ Darton, Philip Wormald, Russell Edward Morris

School/Research organisations

Abstract

Variable temperature high resolution magic angle spinning Si-29 NMR spectroscopy is used to study the phase transition between the low and high temperature versions of pure silica ferrierite. Spectra collected at 133-400 K indicate that the low temperature phase is probably of lower symmetry than that previously reported using single crystal X-ray diffraction results. The NMR spectra around the phase transition are consistent with the description of the high temperature phase as a dynamic average of possible low temperature structures. A comparison of the NMR chemical shifts with the results of previous X-ray diffraction experiments confirms the validity of proposed correlations and indicates how they can be of predictive value in certain cases.

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Original languageEnglish
Pages (from-to)2036-2040
Number of pages5
JournalJournal of Materials Chemistry
Volume14
DOIs
Publication statusPublished - 2004

    Research areas

  • X-RAY-DIFFRACTION, NEGATIVE THERMAL-EXPANSION, SOLID-STATE NMR, QUARTZ, O-17

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